Effect of divalent cations on the kinetics of Fe(III) complexation by organic ligands in natural waters     

Manabu Fujii  Andrew L. Rose  Tatsuo Omura 《Geochimica et cosmochimica acta》2008,72(5):1335-1349

We have investigated the kinetics of Fe(III) complexation by several organic ligands including fulvic acid, citrate and ethylenediaminetetraacetic acid (EDTA). Particular attention was given to examination of the effect of competitive divalent cations (Me: Ca²⁺ and Mg²⁺) at concentrations typical of seawater on the complexation rate. All experiments were conducted in 0.5 M NaCl solution buffered with 2 mM bicarbonate at pH 8.0 in the absence and presence of Me (25 μM-250 mM). The rate constants of complex formation determined by using the competitive ligand (5-sulfosalicylic acid) method combined with visible spectrophotometry ranged from 3.3 × 10⁴ to 3.2 × 10⁶ M⁻¹ s⁻¹. The mechanism of complexation was then examined based on a kinetic model. When EDTA was used as a ligand, Me at concentrations comparable to the ligand markedly retarded the rate of iron complex formation due to the predominance of an adjunctive pathway (where iron-ligand complex is formed via direct association of iron to Me-ligand complex). In contrast, the competing effect of Me on iron complexation by citrate and fulvic acid was observed only when the Me concentration was in excess of the ligand by more than a factor of 10-1000. The kinetic model suggests that iron complexation by fulvic acid occurs predominantly via a disjunctive pathway (where iron complexation by ligand occurs after dissociation of Me from Me-ligand complex) at concentrations of divalent cations and natural organic matter typical of natural waters including seawater and freshwater.  相似文献   

Dynamics of electron beams in a coronal loop and the hard X-ray burst     

Tatsuo Takakura 《Solar physics》1986,104(2):363-389

A numerical simulation has been made for the dynamics of non-thermal electrons (> 10keV) injected with spatial, temporal and velocity distributions into a model coronal loop. The time variations of the spatial intensity distribution and the spectrum for the expected hard X-rays are computed for many models in order to find the important physical parameters for those characteristics.The most important one is the column density of plasma, CD, along the loop. If CD is smaller than 10²⁰ cm^–2, the expected X-rays behave like the solar impulsive hard X-ray bursts, that is the spatial maximum of X-rays shifts to the top of the loop in the later phase of the burst accompanying a spectral softening. On the other hand, if CD is greater than this value, quasi-steady decay appears in the later phase. In this case the intensity distribution of X-rays above about 20 keV along the loop shows a broad maximum away from the loop top giving an extended spatial distribution of hard X-rays, and spectral hardness is kept constant. These characteristics are similar to the solar gradual hard X-ray bursts (the so-called extended burst which is not a hot thermal gradual burst).  相似文献   

A dataset of continental river discharge based on JRA-55 for use in a global ocean circulation model     

Tatsuo Suzuki  Dai Yamazaki  Hiroyuki Tsujino  Yoshiki Komuro  Hideyuki Nakano  Shogo Urakawa 《Journal of Oceanography》2018,74(4):421-429

A dataset of historical river discharge into oceans was created using the CaMa-Flood global river routing model and adjusted runoff from the land component of JRA-55. The major rivers were well resolved with a 0.25° horizontal resolution. The total runoff on each drainage basin exhibits a distinctive bias on decadal time scales. The input runoff data were modified using 5-year low-pass-filtered multiplicative factors to fit the annual mean climatology and decadal variations in the reference dataset. The model incorporated data from 1958 to 2016. The yearly and seasonal variations of the major rivers are well represented by the model.  相似文献   

Tree-ring based hydroclimate reconstruction over northern Vietnam from Fokienia hodginsii: eighteenth century mega-drought and tropical Pacific influence   总被引：1，自引：0，他引：1  

Masaki Sano  Brendan M. Buckley  Tatsuo Sweda 《Climate Dynamics》2009,33(2-3):331-340

We present here the first statistically calibrated and verified tree-ring reconstruction of climate from continental Southeast Asia. The reconstructed variable is March–May (MAM) Palmer Drought Severity Index (PDSI) based on ring widths from 22 trees (42 radial cores) of rare and long-lived conifer, Fokienia hodginsii (Po Mu as locally called) from northern Vietnam. This is the first published tree ring chronology from Vietnam as well as the first for this species. Spanning 535 years, this is the longest cross-dated tree-ring series yet produced from continental Southeast Asia. Response analysis revealed that the annual growth of Fokienia at this site was mostly governed by soil moisture in the pre-monsoon season. The reconstruction passed the calibration-verification tests commonly used in dendroclimatology, and revealed two prominent periods of drought in the mid-eighteenth and late-nineteenth centuries. The former lasted nearly 30 years and was concurrent with a similar drought over northwestern Thailand inferred from teak rings, suggesting a “mega-drought” extending across Indochina in the eighteenth century. Both of our reconstructed droughts are consistent with the periods of warm sea surface temperature (SST) anomalies in the tropical Pacific. Spatial correlation analyses with global SST indicated that ENSO-like anomalies might play a role in modulating droughts over the region, with El Niño (warm) phases resulting in reduced rainfall. However, significant correlation was also seen with SST over the Indian Ocean and the north Pacific, suggesting that ENSO is not the only factor affecting the climate of the area. Spectral analyses revealed significant peaks in the range of 53.9–78.8 years as well as in the ENSO-variability range of 2.0 to 3.2 years.  相似文献   

Mechanism of currents through the straits of the Japan Sea: Mean state and seasonal variation     

Hiroyuki Tsujino  Hideyuki Nakano  Tatsuo Motoi 《Journal of Oceanography》2008,64(1):141-161

The mechanism governing the mean state and the seasonal variation of the transports through the straits of the Japan Sea is studied using a newly presented, simple analytical model and a basin scale general circulation model (GCM). The GCM reproduces the transports through the straits of the Japan Sea realistically owing to its fine horizontal resolution of about 20 km and realistic topography. A series of experiments conducted by changing surface forcing shows that the annual mean wind-driven circulation in the North Pacific Ocean is most responsible for the formation of the mean transports. It is also found that the seasonal variation of the alongshore component of monsoonal wind stress over the North Pacific basin, especially that over the Okhotsk Sea, is responsible for the seasonal variation of the transports. The simple analytical model can explain these simulated features very well. The physical concept of this model is based on the formation of the around-island circulation through the adjustment of coastally trapped waves and Rossby waves and geostrophic control at the narrow straits. It solves the sea surface heights (SSHs) at the edge of each strait and the transport through it. The value of the line integral of the SSH along the island is determined by the baroclinic Rossby waves approaching the island from the east and the alongshore wind stress around the island. The basin scale seasonal variation of SSH along the coast induced by the variation of the alongshore monsoonal wind stress can also be incorporated into this model by giving the SSH anomaly at the northeastern point of the Soya Strait. Thus, it is suggested that both the mean state and the seasonal variation are caused mainly by wind stress forcing. Minor modification by the seasonal heat flux forcing brings the amplitude and the phase of the seasonal variation closer to the observed values.  相似文献   

Definition and characteristic features of a seismically active region (earthquake nest) in the Kanto district     

Tatsuo Usami  Tadao Watanabe 《Pure and Applied Geophysics》1980,118(2):1326-1328

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Interstadial coral reef terraces and relative sea-level changes during marine oxygen isotope stages 3–4, Kikai Island, central Ryukyus, Japan     

Keiichi Sasaki  Akio Omura  Kazuo Murakami  Natsume Sagawa  Toru Nakamori 《Quaternary International》2004,120(1):51

Coral reef terraces are one of the best recorders of relative sea-level changes during the last glacial cycle. Thus far, knowledge of relative sea-level record based on coral reefs during the marine Oxygen Isotope Stage (OIS) 3 has been limited to studies of the Huon Peninsula, Papua New Guinea. High-precision a α-spectrometric ²³⁰Th/²³⁴U dating demonstrated an offlapping sequence of five coral reef complexes, ages of which are 66, 64, 62, 55 and 52 ka, in the northern part of Kikai Island, central Ryukyus of Japan. Interstadial reefs, characterized by deepening-upward sequences of coral assemblages, recorded three hemicycles from transgression to highstand at 52, 62, and 66 ka, during which these reefs were drowned. These highstands in the relative sea-level record can be correlated with the eustatic record reconstructed from the Huon reef terraces and with the interstadials 14, 18, and 19 of the GISP 2 oxygen isotope record. This consistency confirms the Huon sea-level record of OIS 3 and implies that the eustatic sea level responded to the millennial-scale climate changes even during the glacial period of OIS 4.  相似文献   

²³⁰Th/²³⁴U and ¹⁴C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan     

Keiichi  Sasaki  Akio  Omura  Tetsuo  Miwa  Yoshihiro  Tsuji  Hiroki  Matsuda  Toru  Nakamori  Yasufumi  Iryu  Tsutomu  Yamada  Yuri  Sato  Hiroshi  Nakagawa 《Island Arc》2006,15(4):455-467

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.  相似文献   

Interpretation of time characteristics of solar X-ray bursts referring to associated microwave bursts     

Tatsuo Takakura 《Solar physics》1969,6(1):133-150

It has been controversial whether the flare-associated hard X-ray bursts are thermal emission or non-thermal emission. Another controversial point is whether or not the associated microwave impulsive burst originates from the common electrons emitting the hard X-ray burst.It is shown in this paper that both the thermal and non-thermal bremsstrahlung should be taken into account in the quantitative explanation of the time characteristics of the hard X-ray bursts observed so far in the photon energy range of 10–150 keV. It is emphasized that the non-thermal electrons emitting the hard X-rays and those emitting the microwave impulsive burst are not common. The model is as follows, which is also consistent with the radio observations.At the explosive phase of the flare a hot coronal condensation is made, its temperature is generally 10⁷ to 10⁸K, the number density is about 10¹⁰ cm^–3 and the total volume is of the order of 10²⁹ cm³. A small fraction, 10^–3–10^–4, of the thermal electrons is accelerated to have power law distribution. Both the non-thermal and thermal electrons in the sporadic condensation contribute to the X-ray bursts above 10 keV as the bremsstrahlung. Fast decay of the harder X-rays (say, above 20 keV) for a few minutes is attributed to the decay of non-thermal electrons due to collisions with thermal electrons in the hot condensation. Slower decay of the softer X-rays including around 10 keV is attributed to the contribution of thermal component.The summary of this paper was presented at the Symposium on Solar Flares and Space Research, COSPAR, Tokyo, May, 1968.  相似文献   

The self absorption of gyro-synchrotron emission in a magnetic dipole field: Microwave impulsive burst and hard X-ray burst     

Tatsuo Takakura 《Solar physics》1972,26(1):151-175

The gyro-synchrotron emission from a model source with a non-uniform magnetic field is computed taking into account the self absorption. This model seems adequate not only to interpret the radio spectrum and its time variation of microwave impulsive bursts but also to solve the discrepancy between the numbers of non-thermal electrons emitting radio burst and those emitting hard X-ray burst.The decrease of flux of radio burst with decreasing frequency at low microwave frequencies is due to the self absorption and/or the thermal gyro-absorption. In this frequency range, the radio source is optically thick even at weak microwave bursts. The weakness of the bursts may be rather due to the small size of the radio source and/or the weakness of the magnetic field than the small number density of the non-thermal electrons.The time variation of the flux of radio burst may be mainly attributed to the variation of source size in a horizontal direction ( direction) instead of the variation of the number density of non-thermal electrons itself, implying that the acceleration region progressively moves in the horizontal direction leaving the non-thermal electrons behind during the increasing phase of the radio burst.  相似文献